Product ID:085640-00904, #5 FUEL 2.0% S
MSDS Date:08/31/1989
FSC:9150
NIIN:00N024597
MSDS Number: BPLDK

EXXON CO USA, A DIV OF EXXON CORP.

800 BELL ST
HOUSTON, TX 77252-2180
US

Emergency Phone: 713-656-3424/800-424-9300(CHEMTREC)

Info Phone: 713-656-3424/3540

Cage: 29700

EXXON COMPANY U.S.A.

2180 HOUSTON, TX 77252-2180 US

Telephone: 713-656-5949 / 713-656-3424

Cage: 29700

BY GEN ODOR OF HOT PROD. BECAUSE H*2S MAY ACCUM IN

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UPWIND, KEEP THEIR FACES AT LST 2FT FROM

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DOME COVERS. EXPOS TO EXHST FROM BURNING/DIESEL

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SOURCES. KEEP CONTRS CLSD WHEN NOT IN USE. DO NOT

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FIRE OR EXPLOSION HAZARDS, USE APPROP EQUIP.

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WITH SKIN. DANGER! COMBUSTIBLE! MAY FORM HYDROGEN

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OIL-SOAKED. CLEANSE SKIN THORO AFTER CONT,

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READILY REMOVED FROM SKIN BY WATERLESS HAND

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MEANS OF DETECTION BECAUSE SENSE OF SMELL RAPIDLY

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FUEL OIL, RESIDUAL

CAS: 68476-33-5

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Fraction By Weight: 100%

CNTN COMPONENTS/PETROLEUM FRACTIONS WHICH HAVE

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PAINTING TESTS. POTNTL RISKS TO HUMANS CAN BE

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GENERALLY RECOMM FOR PETROLEUM PRODS. LONG-TERM RPTD

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IN AN INCREASED INCIDENCE OF LUNG CANCER.

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DO NOT INDUCE

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WATERCOURSES, OR EXTENSIVE LAND AREAS.

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IGNITE/EXPLODE. KEEP PROD AWAY FROM IGNIT

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DO NOT ATTEMPT TO CLEAN SINCE RESIDUE IS DFCLT

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PROPERLY BUNGED & PROMPTLY RETURNED TO DRUM

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SAFE MANNER AND I/A/W GOVERN REGS. PROD NORMALLY

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UNDER CERTAIN CIRCUMSTANCES, SULFUR CMPDS IN HOT

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EMIT TRACES OF H*2S TEMPORARILY FROM

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W/AN ODOR AT LOW CONC CHARACT OF ROTTEN EGGS &

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LD50 LC50 Mixture:LD50:(ORAL, RAT) >5 G/KG OF BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: HIGH VAP CONC MAY CAUSE
EYE/RESP IRRIT/DIZZ/HDACH/GASPING/NAUS/DISORIENTATION/
UNCON/POSSIBLY DEATH. PRLNG/RPTD CONT W/PROD AT WARM/NEAR AMBIENT
TEMPS MAY CAUSE SKIN IRRIT. PRLNG BRTHG O F 50-100PPM OF H*2S MAY
PRDCE EYE/RESP TRACT IRRIT/HDACH/NERVOUSNESS/NAUS, & ONLY FEW
BREATHS OF HIGH (EFT OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CONC (700-1000PPM) MAY LEAD TO UNCON
& MAY BE FATAL. INHAL OF COMPONENTS OF EXHST FROM BURNING, SUCH AS
CO, MAY CAUSE DEATH AT HIGH CONC. SKIN/EYE: CONT W/HOT PROD MAY
CAUSE THERMAL BURNS. P ROD CONTACTING EYES MAY CAUSE IRRIT. INGEST:
PROD HAS LOW ORDER OF ACUTE ORAL/DERMAL TOX, BUT MINUTE AMTS (SUPP
DATA)
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS.

First Aid:EYES: FLUSH W/CLEAR WATER FOR AT LST 15 MIN OR UNTIL IRRIT
SUBSIDES. IF IRRIT PERSISTS, CALL MD. SKIN: IMMED CONT MD FOR
TREATMENT OF THERMAL BURNS. IN CASE OF CONT W/PROD UNDER OTHER
CNDTNS, WASH THO RO W/SOAP & WATER. REMOVAL OF PROD FROMSKIN MAY BE
AIDED BY USE OF WATERLESS HANDCLEANER. INHAL: REMOVE FROM EXPOS &
CALL MD IMMED. IF BRTHG IS IRREG/STOPPED, START RESUSCITATION.
ADMIN O*2, (ING 6)

Flash Point Method:PMCC
Flash Point:140F,60C
Lower Limits:0.9%
Upper Limits:7%
Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CARBON
DIOXIDE AND VAPORIZING LIQUID TYPE EXTINGUISHING AGENTS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
USE WATER TO KEEP FIRE-EXPOSED CONTRS COOL. IF LEAK/SPILL HAS NOT
IGNITED, USE WATER SPRAY TO (SUPP DATA)
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:RECOVER FREE PROD. ADD SAND/EARTH/OTHER
SUITABLE ABSORB TO SPILL. MINIMIZE BRTHG VAPS/SKIN CONT. OPEN ALL
WINDOWS/DOORS. KEEP PROD OUT OF SEWERS/ WATERCOURSES BY
DIKING/IMPOUNDING. ADVISE AUTH IF PROD HAS ENTERED OR MAY ENTER
SEWERS/ (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:LIQ IS VOLAT & GIVES OFF INVISIBLE
VAPS. LIQ/VAP MAY SETTLE IN LOW AREAS/TRAVEL SOME DIST ALONG
GROUND/SURF TO IGNIT SOURCES WHERE THEY MAY (ING 8)
Other Precautions:"EMPTY" CONTRS RETAIN RESIDUE (LIQ &/OR VAP) & CAN BE
DANGEROUS. DO NOT PRESSURIZE/CUT/WELD/BRAZE/ SOLDER/DRILL/EXPOSE
SUCH CONTRS TO HEAT/FLAME/ SPARKS/STATIC ELECTRICITY/OTHER SOURCES
OF IGNIT; THEY MAY EXPLODE/CAUSE INJURY/DEATH! (ING 9)

Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES WHEN HANDLING HOT
PRODUCT, IF NEEDED, OR WHEN H*2S EXCEEDS PERMISSIBLE LIMITS.
Ventilation:USE LOC EXHST TO CAPTURE VAP/MISTS/FUMES. PROVIDE VENT TO
MINIMIZE INHAL EXPOS/PVNT BUILDUP OF EXPLO CONC OF VAP IN AIR.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:CHEM-RESIST APRON/OTHER IMPERVIOUS CLTHG TO
AVOID CONTAMINATING REGULAR CLTHG, WHICH MAY RSLT IN PRLNG/RPTD
SKIN CONT.
Work Hygienic Practices:REMOVE CONTAMD CLTHG; WASH/DRY-CLEAN BEFORE
REUSE. REMOVE CONTAMD SHOES & THORO CLEAN BEFORE REUSE; DISCARD IF
(ING 22)
Supplemental Safety and Health
FIRE FIGHT PROC: DISPERSE VAPS & TO PROVIDE PROT FOR MEN ATTEMPTING TO
STOP LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS.
MINIMIZE BRTHG OF GASES/VAP/FUMES/DECOMP PRODS. EFTS OF OVERE XP:
ASPIRATED INTO LUNGS DURING INGEST/VOMIT MAY CAUSE MILD TO SEV PULM
INJURY/POSSIBLY DEATH. CHRONIC: PROD MAY (ING 2)

HCC:F4
Boiling Pt:B.P. Text:425F,218C
Vapor Pres:<0.1 @ 20C
Vapor Density:>5
Spec Gravity:0.98 (15.6C)
pH:NEUT
Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE. <0.1%
Appearance and Odor:BLACK LIQUID, STRONG ASPHALTIC ODOR.
Percent Volatiles by Volume:16

Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG OXIDANTS SUCH AS LIQUID CHLORINE, CONCENTRATED
OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FIRE CNDTNS: FUMES, SMOKE, CO, H*2S,
SO*X, ALDEHYDES AND OTHER DECOMPOSITION PRODS, IN CASE OF
INCOMPLETE COMBUSTION.

Waste Disposal Methods:ASSURE CONFORMITY W/APPLICABLE GOVERNMENTAL
REGULATIONS. CONTINUE TO OBSERVE PRECAUTIONS FOR VOLATILE,
COMBUSTIBLE VAPORS FROM ABSORBED MATERIAL. DISPOSAL MUST BE I/A/W
FEDERAL, STATE, AND LOCAL REGUL ATIONS .

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particular situation.